State Equation Solution

A state equation solution describes how the internal variables of a dynamic system change over time from an initial condition and applied inputs. In engineering state-space modeling, the system is represented by a first-order equation such as ẋ = Ax + Bu, where the state-transition matrix, commonly written as e^(At), propagates the initial state while an input-response term accounts for external forcing. These solutions support analysis and simulation of mechanical, electrical, aerospace, and control systems, including prediction of transient behavior, stability assessment, and controller design. They also provide a systematic foundation for numerical computation when analytical solutions are impractical.

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JoVE Core - Electrical Engineering

Difference Equation Solution using z-Transform

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2024

The z-transform is a powerful tool for analyzing practical discrete-time systems, often represented by linear difference equations. Solving a higher-order difference equation requires knowledge of the input signal and the initial conditions up to one term less than the order of the equation. The z-transform facilitates handling delayed signals by shifting the signal in the z-domain, which corresponds to delaying the signal in the time domain, and advancing signals by similarly shifting in the...

Chemical Equations

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2020

Chemical equations represent the identities and relative quantities of substances involved in a chemical reaction. The substances undergoing reaction are called reactants, and their formulas are placed on the left side of the equation. The substances generated by the reaction are called products, and their formulas are placed on the right side of the equation. Plus signs (+) separate individual reactant and product formulas, and an arrow (→) separates the reactant and product (left and right)...

The Nernst Equation

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2020

Nonstandard Reaction Conditions The interconnection between standard cell potentials and various thermodynamic parameters such as the standard free energy change ΔG° and equilibrium constant K has been previously explored. For example, a redox reaction involving zinc(II) and tin(II) ions at 1 M concentration with Eºcell = +0.291 V and ΔG° = −56.2 kJ is spontaneous. Discharge of this cell, however, results in a change in the reactant concentration and a steady decrease of the cell potential. At...

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JoVE Core - Chemistry
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Thermochemical Equations

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2020

For a chemical reaction (the system) carried out at constant pressure – with the only work done caused by expansion or contraction – the enthalpy of reaction (also called the heat of reaction, ΔHrxn) is equal to the heat exchanged with the surroundings (qp). The change in enthalpy is an extensive property, and it depends on the amounts of the reactants participating in the reaction (or the number of moles of reactants). The change in enthalpy is specific to the reaction, and the physical...

Henderson-Hasselbalch Equation

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2020

The ionization-constant expression for a solution of a weak acid can be written as: Rearranging to solve for [H3O+] yields: Taking the negative logarithm of both sides of this equation gives which can be written as where pKa is the negative of the logarithm of the ionization constant of the weak acid (pKa = −log Ka). This equation relates the pH, the ionization constant of a weak acid, and the concentrations of the weak conjugate acid-base pair in a buffered solution. Scientists often use...

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