Shape Memory Polymer

Shape memory polymers are smart, stimuli-responsive materials that can be deformed into a temporary shape and later recover a programmed permanent shape, making them valuable in engineering designs that require controlled motion or deployment. Their behavior relies on a polymer network with stable structural segments and switchable segments that soften or reorganize when exposed to a stimulus, commonly heat, allowing stored elastic energy to drive shape recovery. Engineers use these materials in deployable structures, actuators, biomedical devices, and minimally invasive systems, where low density, flexibility, and tunable transition temperatures can support compact fabrication and remote or self-actuated operation.

Shape Memory Polymer - Related Videos

Research

JoVE Journal - Bioengineering

Shape Memory Polymers for Active Cell Culture

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Cited by 25 •

2011

A method for developing cell culture substrates with the ability to change topography during culture is described. The method makes use of smart materials known as shape memory polymers that have the ability to memorize a permanent shape. This concept is adaptable to a wide range of materials and applications.

Fabrication of a Bioactive, PCL-based "Self-fitting" Shape Memory Polymer Scaffold

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Cited by 33 •

2015

Scaffolds capable of fitting within cranio-maxillofacial (CMF) bone defects while exhibiting osteoconductivity and bioactivity are of interest. This protocol describes the preparation of a shape memory scaffold based on polycaprolactone diacrylate (PCL-DA) using a solvent-casting particulate-leaching (SCPL) method employing a fused salt template and application of a bioactive polydopamine coating.

Research

JoVE Journal - Engineering
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Controlling the Size, Shape and Stability of Supramolecular Polymers in Water

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Cited by 13 •

2012

The goal of this experiment is to determine and control the size, shape and stability of self-assembled discotic amphiphiles in water. For aqueous based supramolecular polymers such level of control is very difficult. We apply a strategy using both repulsive and attractive interactions. The experimental techniques applied to characterize this system are broadly applicable.

Experimental Methods for Investigation of Shape Memory Based Elastocaloric Cooling Processes and Model Validation

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Cited by 8 •

2016

Experimental methods for investigation of solid state cooling processes and characterization of elastocaloric material properties of Shape Memory Alloys (SMA) are presented. A custom-built test rig has been designed for controlling and comprehensive monitoring of elastocaloric cooling processes. Furthermore, it provides a validation platform for thermomechanically coupled modeling approaches.

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers

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2022

Here, we describe protocols for the preparation of trans-cyclobutane fused cyclooctenes (tCBCO), their polymerization to prepare depolymerizable olefinic polymers, and the depolymerization of these polymers under mild conditions. Additionally, protocols for the preparation of depolymerizable networks and compression molding of rigid linear plastics based on this system are described.

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