Emulsion Polymerization

Emulsion polymerization is a heterogeneous method for producing polymers by converting water-insoluble monomers into fine polymer particles dispersed in water, making it important for efficient and scalable materials manufacturing. A surfactant forms micelles or stabilizes growing particles, while a water-soluble initiator generates radicals that start polymerization in the aqueous phase or within monomer-swollen particles. Heat, agitation, monomer concentration, initiator level, and surfactant content influence particle size, reaction rate, and latex stability. In engineering, the process produces aqueous polymer dispersions used in paints, coatings, adhesives, synthetic rubbers, and plastics, often reducing the need for organic solvents and enabling control over material properties.

Emulsion Polymerization - Related Videos

Research

JoVE Journal - Immunology and Infection

A Rapid, Simple, and Standardized Homogenization Method to Prepare Antigen/Adjuvant Emulsions for Inducing Experimental Autoimmune Encephalomyelitis

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Cited by 3 •

2022

To induce experimental autoimmune encephalomyelitis, an animal model of multiple sclerosis, mice are immunized with a water-in-oil emulsion containing an autoantigen and complete Freund's adjuvant. While several protocols exist for the preparation of these emulsions, a rapid, simple, and standardized homogenization protocol for emulsion preparation is presented here.

Education

JoVE Science Education - Chemistry

Polymerization

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2023

Source: Vy M. Dong and Jan Riedel, Department of Chemistry, University of California, Irvine, CA Polymers are made from macromolecules, which are composed of repeating units (the so called monomeric units). In our modern world, polymers play an important role. One of the first important polymers was nylon, which is a polyamide. It found widespread application in tooth brushes and stockings.

Glass-Based Devices to Generate Drops and Emulsions

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Cited by 1 •

2022

Here, a protocol to manufacture glass-based microfluidic devices used for generating highly monodisperse emulsions with controlled drop size is presented.

Preparing an Antigen-Adjuvant Emulsion to Induce Autoimmune Encephalomyelitis

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2025

This video demonstrates an efficient homogenization technique to generate an antigen-adjuvant emulsion to induce experimental autoimmune encephalomyelitis (EAE) in a murine model. The emulsion contains an autoantigen — myelin oligodendrocyte glycoprotein (MOG) — in the water phase, surrounded by a continuous oil phase comprising an inactivated pathogenic bacteria. The emulsion ensures a sustained release of antigens for a prolonged immune response.

Minimum Burning Pressures of Water-based Emulsion Explosives

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2017

We present an apparatus based on hot-wire ignition in a pressurized enclosure and an associated methodology to measure the minimum pressure required to induce sustained combustion in water-based emulsion explosives. This method improves product characterization to allow one to use them more safely during pumping and mixing operations.

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