Anionic Ligands

Anionic ligands are negatively charged ions or molecular groups that bind to a central metal atom or ion in a coordination complex, helping determine its structure and reactivity. They form coordinate bonds by donating one or more lone pairs to the metal, while their charge influences the complex’s overall charge, geometry, electronic properties, and stability; examples include chloride, hydroxide, cyanide, and alkoxide ligands. In coordination chemistry, anionic ligands are important for interpreting bonding and oxidation states and for designing catalysts, magnetic materials, bioinorganic models, and compounds with targeted optical or redox behavior.

Anionic Ligands - Related Videos

Education

JoVE Core - Chemistry

Metal-Ligand Bonds

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2020

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes. In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...

Research

JoVE Journal - Chemistry

Sulfate Separation by Selective Crystallization with a Bis-iminoguanidinium Ligand

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2016

A protocol for in situ aqueous synthesis of a bis(iminoguanidinium) ligand and its utilization in selective separation of sulfate is presented.

Ligand Binding Sites

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2020

Proteins are dynamic macromolecules that carry out a wide variety of essential processes; however, the activities of most proteins depend on their interactions with other molecules or ions, known as ligands. Protein-ligand interactions are quite specific; even though numerous potential ligands surround a cellular protein at any given time, only a particular ligand can bind to that protein. Moreover, a ligand binds only to a dedicated area on the surface of the protein, known as the...

Anion Exchange Resin–Based Detection of Viruses from Bioaerosols

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2026

Source: Schaeffer, J. W., Chandler, et al. Detection of Viruses from Bioaerosols Using Anion Exchange Resin. J. Vis. Exp. (2018).This video demonstrates the detection of viruses from bioaerosols using an anion exchange resin. A liquid impinger containing the resin is used to capture viruses from the air. The resin is collected and treated with a virus lysis buffer containing carrier RNA. The lysate is transferred to a microcentrifuge tube for viral RNA isolation, followed by qRT-PCR to amplify...

Research

JoVE Journal - Immunology and Infection

Alternative Methods for the Detection of Superoxide Anion Generation in Platelets

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2024

The generation of superoxide anion is essential for the stimulation of platelets and, if dysregulated, critical for thrombotic diseases. Here, we present three protocols for the selective detection of superoxide anions and the study of redox-dependent platelet regulation.

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